What do you see with her leg exactly? It usually takes me a while to see all the problems. All I can see right now is her calf is a bit large.
Her right foot does stick out a bit but it's not completely unrealistic as high heels can enforce an extreme leg posture. The effect is visible in this image http://chicuta.deviantart.com/art/Tequileira-89364047
I just looked at her sprite from the enemy catalog on the ds, which I cannot find an online version of. She strikes a pose similar to this in the game, but the sieg heil look came about when I changed her from sultry to bitchy.